While some oxalate enters the Bayer process with bauxite as oxalic acid adsorbed on various minerals, the majority is created by the oxidation and pyrolysis of bauxite organics under Bayer digestion conditions. The rate of its formation in digestion is principally related to the bauxite organic carbon concentration and composition, and to the ...
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The Bayer's process of alumina extraction involves digestion of bauxite with caustic soda at temperatures ranging from 100 to 250 °C, depending on the form of alumina in the bauxite, gibbsitic, boehmitic or diasporic. ... Concentration of bauxite fines via gravity concentration. Rem. Revista Escola de Minas 62(3), 277281 (2009 ...
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Baeyer's process is used to leach Red Bauxite, which has Fe2O3 as the chief impurity. Serpeck's process, on the other hand, is used to leach White Bauxite, which has Silica as main impurity. Both are efficient for their respective ores. But Baeyer's process is more frequently used, as Bauxite, more often than not, is also a source of Gallium ...
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A simplified process flow diagram of the Bayer process used at the Wagerup refinery is presented in Figure 6. Bauxite Grinding and Slurry Storage Bauxite is ground to less than mm particle size at the refinery, using semiautogenous grinding mills (SAG and/or Ball mills) to ensure sufficient solidliquid contact during the
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Bayer process, bauxite is mixed with caustic soda, or sodium hydroxide, and heated under pressure. ... The maximum concentration of alumina dissolved in the caustic, known as the ratio (as Al 2 O ...
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ALUMINA FROM BAUXITE: THE BAYER PROCESS. Bauxite, the principal ore used for aluminum smelting, is named after Les Baux, Provence, the village where the first deposits were discovered. Bauxite contains hydrated alumina equivalent to as much as 4060% Al 2 O 3, and is free of the other siliceous materials leached out over time. However it ...
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In the Bayer process, the digestion temperature is an important factor in determining the alumina digestion rate. In this study, the digestion efficiency of the ore at different temperatures was investigated under the following conditions: caustic concentration 240 g/L, initial molar ratio, lime addition 15%, molar ratio of digested liquid ...
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on the Bayer process. Predesilication characteristic of the bauxite, the effects of digestion temperature and retention time, concentration of Na20 and amount of CaO addition on AI20 3 digestion efficiency in Bayer process, the settling characteristics ofthe red mud were determined. The bauxite in
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Bayer's method: In this method, bauxite powder is taken and concentrated (45%) and sodium hydroxide solution is added and then heated in a closed vessel at 433 K temperature and 5 to 6 bars of pressure, for 6 to 8 hours, so that aluminium oxide present in bauxite is converted into sodium aluminate which is soluble in water. In bauxite, in ...
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This paper proposes a novel approach to sulfur removal by adding aluminum in the bayer process of highsulfur bauxite. The effects of aluminum dosage on the concentrations of different valence sulfur in sodium aluminate solution were investigated at length to find that highvalence sulfur (S 2 O 3 2−, SO 3 2−, SO 4 2−) concentration in sodium aluminate solution decreases, but the ...
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Bayer's process for concentration of bauxite. Ans. Bayer's process is used to obtain pure aluminium oxide from bauxite ore. The bauxite ore is concentrated by chemical separation. Bauxite contains impurities like iron oxide and silica. The bauxite ore is powdered and heated with sodium hydroxide under high pressure in the furnace.
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The alumina extraction and iron minerals' comprehensive utilization of technology that could replace the current Bayer process have not yet been formed. In the current Bayer digestion process, gibbsitic bauxite was digested at a temperature, alkali concentration, and time of 100150 °C, 120190 g/L, and 1090 min, respectively.
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Bauxite Al 2 O 2 O; Corundum Al 2 O 3; Cryolite Na 3 AlF 6; Metallurgy of Aluminium. Aluminium is mostly extracted from its bauxite ore. Dressing of Ore. The ore is mechanically crushed and pulverized. Concentration of ore. The bauxite ore contains ferric oxide and silica as impurities.
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Bayer's method for the extraction of Alumina: ∙ Conversion of impure bauxite to sodium aluminate; Bauxite in the powdered form is added to conc. sodium hydroxide and then heated in a closed vessel at 433 K and 5−6 bar pressure for 6 −8 hours. The aluminium oxide in bauxite is converted to sodium aluminate which is soluble in water.
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Bauxite is the major ore for aluminum production, and mainly consists of aluminum hydroxides and oxidehydroxides, iron oxides and oxidehydroxides, clay minerals, silicon dioxide and titanium dioxide, often in various polymorphic mineral phases. 7,8 The concentration of gallium in bauxite ranges from below 10 ppm to over 800 ppm, with an ...
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Lime is an essential reagent required in various process steps of the Bayer process, in which bauxite ore is converted into alumina (Whittington et al. 1997), as illustrated in Fig. is used for improving conversion of goethite to hematite and dissolution of boehmite and diaspore during digestion; control of liquor impurities such as silica, oxalate, titanium and phosphorous; minimising ...
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During the digestion process of the Bayer method, lithium and gallium in bauxite will enter into the sodium aluminate solution (Tang et al. 2020; Xu et al. 2018), which will return to the digestion process for recycling after the precipitation of aluminum hydroxide from the decomposition of crystal to a large amount of red mud discharge, most of the lithium and gallium in the ...
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Bayer process solution, in which a bauxite is subsequently leach ed for alumina extraction, and an alkaline solution with a concentration of 400 g L 1 Na 2 O, to c arry out similar investigations.
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The Bayer process is the principal industrial means of refining bauxite to produce alumina (aluminium oxide) and was developed by Carl Josef Bayer. Bauxite, the most important ore of aluminium, contains only 3060% aluminium oxide (Al 2 O 3 ), the rest being a mixture of silica, various iron oxides, and titanium dioxide. [1]
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The Bayer process for alumina production generates more than 160 million tons of bauxite residue annually. The current global stockpiles of bauxite residue have reached more than 4 billion tons with less than 2% annual recycling rate. Critical elements such as Sc and Y present an opportunity to explore bauxite residue as a secondary resource; however, low concentration affects the process ...
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temperature, retention time, free caustic concentration and molar ratio of solution. Based on the experimental data, the calculation models of raw material consumption for different bauxites were established. Under the same basic raw material price, lowtemperature Bayer process was suitable for treating Bauxite1 and Bauxite3.
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The Bayer process is used for refining bauxite to smelting grade alumina (Al 2 O 3), the precursor to aluminium. ... (Na2Ox or K2Ox) increases with an increase in concentration of the counter ion ...
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Alumina is extracted from bauxite by the Bayer process. The waste slurry generated in this process is called red mud and its solid fraction is called bauxite residue. About 12 metric tonnes of bauxite residue is generated for each tonne of alumina produced ( Kumar et al., 2006 ). The global annual generation of bauxite residue is around 120 ...
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The aim of this work was to achieve an understanding of the distribution of selected bauxite trace elements (gallium (Ga), vanadium (V), arsenic (As), chromium (Cr), rare earth elements (REEs), scandium (Sc)) in the Bayer process. The assessment was designed as a case study in an alumina plant in operation to provide an overview of the trace elements behaviour in an actual industrial setup.
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Bauxite is the principal ore of aluminium. The impurities present in bauxite are SiO2, iron oxides and titanium oxide (T iO2). Concentration is carried out by heating the powdered ore with a concentrated solution of NaOH at 473 523 K and 35 36 bar pressure. This process is called digestion. Al2O3 is extracted out as sodium aluminate.
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The Bayer process is a chemical process for refining aluminium hydroxide, Al(OH) 3 from bauxite; this aluminium hydroxide is subsequently calcined to produce alumina, Al 2 O 3 . The basis of the ...
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The slurry from desilication is mixed with NaOH (P13/MX101) up to concentration of 10%, ... The Bayer process is used for refining bauxite to smelting grade alumina (Al 2 O 3), the precursor to ...
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For the same grade of bauxite ore, using the traditional Bayer process, the theoretical maximum alumina dissolution rate is % and the Na 2 O mass fraction in the slag is about % (A/S = 1 and N/S = in the red mud), while the actual dissolution rate of the Bayer process bauxite ore in this alumina plant is about 70%, which shows ...
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The bauxite slurry typically has lower caustic concentration liquor as the bauxite is received with some humidity that acts to dilute the liquor which mixes with it at the start of the process. Thus, the step to single stream digestion not only provides an extra heat sink to improve energy efficiency, it also reduces the heater tube caustic ...
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The Bayer process is the main method of alumina production worldwide. The use of lowquality bauxites for alumina production results in the formation of a significant amount of technogenic waste—bauxite residue (BR). The Bayer reductive method is one possible way to eliminate BR stockpiling, but it requires highpressure leaching at temperatures higher than 220 °C.
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The Bayer Process was invented and patented in 1887 by Austrian scientist Karl Josef Bayer. Two to three tonnes of bauxite are required to produce one tonne of alumina. 90% of the global alumina supply of around 90 million tonnes is used in aluminium production.
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This dissolves aluminium oxide present in bauxite due to the formation of sodium aluminate, (N a A l O 2 ). A l 2 O 2 . H 2 O + 2 N a O H → 2 N a A l O 2 + 3 H 2 O. Since, N a O H a strong reducing agent, it is used in Bayer's process.
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The Bayer process is the principal method for production of alumina from bauxite worldwide. The modern version of the process (developed in the 1880's) still maintains
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Fig. 2 illustrated the main process of extracting alumina from bauxite by Bayer process and the alkali sources of Bayer bauxite residue. Table 3, Table 4 summarized the main elements and mineralogical compositions of different types of bauxite, as well as the Bayer process parameters applicable to them (Ruys, 2019). It can be concluded that the ...
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